Transport in Cathode of Lithium-Ion Cells

Article Preview

Abstract:

A mathematical model for the transport in cathode of a lithium-ion cell is developed and analytical solutions to the model equations are obtained. The derived equation is tested by fitting it to published experimental discharge characteristics. Wherever possible, the values of the relevant parameters are obtained from the same literature from which the discharge characteristics were obtained. The agreement between the predicted and the experimental discharge curves are measured statistically using t-test. Since the discharge characteristics are usually plotted as voltage versus time or capacity or even state-of-discharge, hence the expression for the cell voltage has been derived.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

101-104

Citation:

Online since:

June 2006

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2006 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P. Georen and G. Lindbergh, Electrochim. Acta 47 (2001), p.577.

Google Scholar

[2] J. Newman and W. Tiedemann, AIChE J., 21 (1975), p.25.

Google Scholar

[3] J. Newman, Electrochemical Systems, Prentice Hall, Englewood Cliffs, New Jersey (1991).

Google Scholar

[4] T. F. Fuller, M. Doyle and J. Newman, J. Electrochem. Soc., 140 (1993) p.1526.

Google Scholar

[5] M. Doyle and J. Newman, J. Appl. Electrochem., 27 (1997), p.846.

Google Scholar

[6] T. F. Fuller, M. Doyle and J. Newman, J. Electrochem. Soc., 141 (1994), p.1.

Google Scholar

[7] Doyle, M. and Newman, J., J. Electrochem. Soc., 143 (1996), p.1890.

Google Scholar

[8] R. Darling and J. Newman, J. Electrochem. Soc., 145 (1998), p.990.

Google Scholar

[9] P. De Vidts and R. E. White, J. Electrochem. Soc., 142 (1995) p.1509.

Google Scholar

[10] M. W. Verbrugge and B. J. Koch, J. Electrochem. Soc., 143 (1996), p.24.

Google Scholar

[11] G. G. Botte, B. A. Johnson and R. E. White, J. Electrochem. Soc., 146 (1999), p.914.

Google Scholar

[12] P. M. Gomadam, J. W. Weidner, R. A. Dougal and R.E. White, J. Power Sources, 110 (2002), p.267.

Google Scholar

[13] P. Ramadass, B. Haran, R. E. White and B. N. Popov, J. Power Sources, 123 (2003), p.230.

Google Scholar

[14] P. Arora, M. Doyle, A. S. Gozdz, R. E. White and J. Newman, J. Power Sources, 88 (2000), p.219.

Google Scholar