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Exciton-Phonon Interaction in CuAlS2 Powders

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Abstract:

High-resolution photoluminescence (PL) measurement was carried out for copper aluminum disulfide (CuAlS2) powder at 12 K. Several sharp PL lines were observed in the range from 3.580 to 3.320 eV. The emission peaks at photon energies from 3.566 to 3.459 eV were attributed to free-exciton (FE) and bound-excitons (BE). The several weak emissions at below 3.476 eV were clarified to be phonon replicas (PR) by Raman scattering and in the viewpoint of exciton-phonon interaction. We observed the one, two and three-phonon replicas related to E(LO, TO) and B2(LO, TO) vibrational modes in chalcopyrite structure. It was suggested that the strong interaction between excitons and optical phonons took place in obtained CuAlS2 powder.

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Periodical:

Advanced Materials Research (Volumes 11-12)

Pages:

175-178

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.11-12.175

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Online since:

February 2006

Authors:

Yuichiro Kuroki, Minoru Osada, Ariyuki Kato, Tomoichiro Okamoto, Masasuke Takata

Keywords:

Chalcopyrite, CuAIS2, Exciton-Phonon Interaction, Photoluminescence (PL), Raman Spectroscopy

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] J.L. Shay and J.H. Wernick, in: Ternary Chalcopyrite Semiconductors: Growth, Electronic Properties, and Applications (Pergamon, Oxford, 1975), p.118.

DOI: 10.1016/b978-0-08-017883-7.50006-8

Google Scholar

[2] S. Chichibu, S. Shirakata, S. Isomura and H. Nakanishi: Jpn. J. Appl. Phys. Vol. 36 (1997), p.1703.

Google Scholar

[3] Y. Chen, D.M. Bagnall, H. Koh, K. Park, K. Hiraga, Z. Zhu and T. Yao: J. Appl. Phys. Vol. 84 (1998), p.3912.

Google Scholar

[4] S. Shirakata, I. Aksenov, K. Sato and S. Isomura: Jpn. J. Appl. Phys. Vol. 31 (1992), p. L1071.

Google Scholar

[5] Y. Kuroki, T. Okamoto and M. Takata: Key Eng. Mater. Vol. 301 (2005), p.177.

Google Scholar

[6] Y. Kuroki, A. Kato, T. Okamoto and M. Takata: to be submitted in J. Electroceram.

Google Scholar

[7] Y. Kuroki, T. Okamoto, S. Ohara and M. Takata: Key Eng. Mater. Vol. 269 (2004), p.95.

Google Scholar

[8] D. Nezaki, T. Okamoto and M. Takata: Key Eng. Mater. Vol. 228-229 (2002), p.241.

Google Scholar

[9] K. Minato, D. Nezaki, T. Okamoto and M. Takata: Key Eng. Mater. Vol. 248 (2003), p.95.

Google Scholar

[10] D. Kovalev, B. Averboukh, D. Volm, B.K. Meyer, H. Amano and I. Akasaki: Phys. Rev. Vol. B54 (1996), p.2518.

DOI: 10.1103/physrevb.54.2518

Google Scholar

[11] B.H. Bairamov, A. Aydinli, I.V. Bodnar', Yu.V. Rud', V.K. Nogoduyko and V.V. Toporov: J. Appl. Phys. Vol. 80 (1996), p.5564.

DOI: 10.1063/1.365546

Google Scholar

[12] L. Roa, J. González, J.C. Chervin and A. Chevy: Phys. Stat. Sol. B Vol. 211 (1999), p.429.

Google Scholar

[13] H. Frohlich: Adv. Phys. Vol. 3 (1954), p.325.

Google Scholar