Hot Corrosion Monitoring of Waste Incineration Corrosion Processes Using Electrochemical Techniques

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Abstract:

In order to evaluate the damage of molten salt mixtures in waste incineration environments, the alloy 625 was exposed to a molten KCl-ZnCl2 mixture at 650 °C for 200 hours. The corrosion process was monitored by electrochemical impedance spectroscopy (EIS). After exposure the corrosion products were analyzed by X-ray diffraction and SEM. Two different electrochemical impedance models were found to describe the electrochemical processes. In the early stages of corrosion the alloy developed a protective Cr2O3 scale which turned into a porous spinel oxide scale after 100 hours.

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Materials Science Forum (Volumes 522-523)

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531-538

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August 2006

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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