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Hot Corrosion Monitoring of Waste Incineration Corrosion Processes Using Electrochemical Techniques
Abstract:
In order to evaluate the damage of molten salt mixtures in waste incineration environments, the alloy 625 was exposed to a molten KCl-ZnCl2 mixture at 650 °C for 200 hours. The corrosion process was monitored by electrochemical impedance spectroscopy (EIS). After exposure the corrosion products were analyzed by X-ray diffraction and SEM. Two different electrochemical impedance models were found to describe the electrochemical processes. In the early stages of corrosion the alloy developed a protective Cr2O3 scale which turned into a porous spinel oxide scale after 100 hours.
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531-538
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August 2006
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© 2006 Trans Tech Publications Ltd. All Rights Reserved
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