Study on the Synthesis of Long Afterglow Nano-Phosphors SrAl2O4:Eu,Dy by Microemulsion Method

Article Preview

Abstract:

To gain nanometer SrAl2O4:Eu,Dy phosphors, uniform fine precursors of Eu and Dy ion doping strontium aluminate were prepared by microemulsion technology. Using as-synthesized stuff, long afterglow phosphors SrAl2O4:Eu,Dy were obtained after sintered at 1200°C. TEM characterization showed the morphology of their grains is sphere-shaped with size less then 100nm. XRD analysis illuminated the crystal structure of SrAl2O4:Eu2+, Dy3+ phosphors is monoclinic. Fluorometry examination detected the peak in emitting spectrum is at 510nm, and at 310nm in exciting spectrum, which both have little blue shift contrasting to the same kind of phosphors synthesized by solid-state reaction method. Finally, the major parameters influencing the grain size of prepared phosphor powders were made a discussion.

You might also be interested in these eBooks

Info:

Periodical:

Key Engineering Materials (Volumes 336-338)

Pages:

613-615

Citation:

Online since:

April 2007

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2007 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] T. Matusuazawa, Y. Aoki and N. Takeuchi: J. Electrochem. Soc. Vol. 143 (1996), p.62.

Google Scholar

[2] Y.H. Lin, Z.T. Zhang and Z.L. Tang: Mater. Chem. Phys. Vol. 70 (2001), p.156.

Google Scholar

[3] M.D. Tang: Luminescence and Illumination (Chinese), No. 2 (2003), p.8.

Google Scholar

[4] Y. Li and Y. Xiong. J. Microelectronics Vol. 35 (2004), p.379.

Google Scholar

[5] T. Peng, H. Yang and X. Pu: Mater. Lett. Vol. 58 (2004), p.352.

Google Scholar

[6] T. Kutty and R. Jagannathan: Mater. Res. Bull. Vol. 25 (1990), p.1355.

Google Scholar

[7] M.H. Lee and S.C. Yi: J. Electrochem. Soc. Vol. 147 (2000), p.31.

Google Scholar

[8] F. Thomas and K.L. Abld: Chem. Soc. Faraday Trans. Vol. 86 (1990), p.3757.

Google Scholar

[9] Y.C. Zhai, X. Zhang and J.Z. Li: Chin. Rare-earth Trans. Vol. 21 (2003), p.205. Fig. 4. Influence of water-to-surfactant molar ratios on mean diameters of synthesized product particles.

Google Scholar