Fabrication of Magnetic Iron-Hercynite Composites by Reaction Sintering

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Abstract:

Iron-hercynite composite was synthesized from Al and Fe3O4 powders by reaction sintering at ~1350oC, or by arc-melting. In reaction sintering, a three-step displacement reaction between Al and Fe3O4 was identified. In arc-melting, we observed that molten iron and hercynite segregated from each other readily. Magnetization of the extracted hercynite from the arc-melted sample was 4 emu/g, smaller than those previously reported, and this can be explained by the variations of the stoichiometric ratio and the degree of inversion of the spinel structure in the hercynite products.

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Key Engineering Materials (Volumes 334-335)

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309-312

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March 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] P.M. Botta, R.C. Mercader, E.F. Aglietti and J.M. Porto Lopez, Scripta Materialia 48 (2003), pp.1093-1098.

DOI: 10.1016/s1359-6462(02)00630-9

Google Scholar

[2] P. M. Botta, P. G. Bercoff, E. F. Aglietti, H. R. Bertorello, J. M. Porto Lopez, Journal of Materials Science 37 (2002), pp.2563-2568.

DOI: 10.1023/a:1015412211898

Google Scholar

[3] P.M. Botta, E. F. Aglietti, J. M. Porto Lopez, Materials Chemistry and Physics 76 (2002), pp.104-109.

Google Scholar

[4] P.M. Botta, E. F. Aglietti, J. M. Porto Lopez, Thermochimica Acta 363 (2000), pp.143-147.

Google Scholar

[5] Paesano Jr., C.K. Matsuda, J.B.M. da Cunha, M.A.Z. Vasconcellos, B. Hallouche and S.L. Silva, Journal of Magnetism and Magnetic Materials 264 (2003), pp.264-274.

DOI: 10.1016/s0304-8853(03)00215-4

Google Scholar

[6] C.M. Yagnik, H.B. Mathur, Journal of Physics C: Solid State Physics 1 (1968), pp.469-472.

Google Scholar