Morphology of Rotationally Moulded Microfibril Reinforced Composites and its Effect on Product Performance

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Abstract:

Rotational moulding (rotomoulding) is one of the fastest growing plastics manufacturing processes using linear polyethylenes dominantly as raw materials. However, due to their modest mechanical properties, rotational moulders worldwide are keen to develop stronger and stiffer materials. In the present study, an attempt was undertaken to apply the concept of microfibril reinforced composites (MFCs) for improving the material performance. Melt blended and subsequently cold drawn and undrawn linear medium density polyethylene (LMDPE) with either poly(ethylene terephthalate) or poly(ethylene naphthalate) possessing MFC structure were mixed with neat LMDPE and thereafter processed via rotational moulding. The rotomoulded samples were characterised morphologically and tested mechanically. The obtained unsatisfactory mechanical characteristics led to the subsequent morphological study which revealed some interesting phenomena for the rotomoulded products containing MFC blends.

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Key Engineering Materials (Volumes 334-335)

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349-352

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March 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] R.J. Crawford: Rotational moulding of plastics (Research Studies Press LTD, 1996).

Google Scholar

[2] D. Martin, P Halley, R. Truss and S. Meusburger: Rotation, January - February (2001), p.44.

Google Scholar

[3] R.J. Crawford and A. Robert: The 3rd Asian-Australasian Conference on Composite Materials (ACCM-3), Auckland, New Zealand (2002), p.1.

Google Scholar

[4] D.R. Blackburn and O.K. Ademosu: 9th International Conference on Fibre Reinforced Composites (FRC 2002), University of Newcastle, UK (2002), p.402.

Google Scholar

[5] J. Ward, S. Panigrahi, L.G. Tabil, W.J. Crerar and T. Powell: An ASAE Meeting Presentation, Paper No: MBSK 02-209 (2002).

Google Scholar

[6] D.J. Martin, P. Halley, R. Truss, M. Murphy, S. Meusburger and O. Jackson: ACUN-4, Composite Systems - Macrocomposites, Microcomposites, Nanocomposites, UNSW, Sydney, Australia (2002).

Google Scholar

[7] D. Martin, P. Halley, R. Truss, M. Murphy, S. Meusburger and O. Jackson: ANTEC 2002 Annual Technical Conference, USA (2002), p.1.

Google Scholar

[8] W. Yan, R.J.T. Lin, S. Bickerton and D. Bhattacharyya: Mater. Sci. Forum 437-438 (2003), p.235.

Google Scholar

[9] J.M. Murphy, R. Truss, P. Halley, D. Martin and C.L. Ang: ANTEC 2003 Conference Proceedings (2003), p.1189.

Google Scholar

[10] W. Yan, R.J.T. Lin and D. Bhattacharyya: Comp. Sci. Technol. on-line (2006).

Google Scholar

[11] M. Evstatiev, N. Nicolov and S. Fakirov: Polymer 37(20) (1996), p.4455.

Google Scholar

[12] S. Fakirov, M. Evstatiev, K. Friedrich: in: Handbook of Thermoplastic Polyesters, edited by S. Fakirov, Vol. 2, Chapter 23, Wiley-VCH, Weinheim (2002).

Google Scholar

[13] M. Evstatiev, S. Fakirov, B. Krasteva, K. Friedrich, J. Covas and A. Cunha: Polym. Eng. Sci. 42 (2002), p.826.

DOI: 10.1002/pen.10994

Google Scholar

[14] Z.M. Li, M.B. Yang, B.H. Xe, J.M. Feng and R. Huang: Polym. Eng. Sci. 43(3) (2003), p.615.

Google Scholar

[15] S. Fakirov, H. Kamo, M. Evstatiev and K. Friedrich: J. Macromol. Sci. -Phys. 43 (2004), p.775.

Google Scholar

[16] K. Friedrich, M. Evstatiev, S. Fakirov, O. Evstatiev, M. Ishii and M. Harrass: Comp. Sci. Technol., 65(1) (2005), p.107.

Google Scholar

[17] Z.M. Li, M.B. Yang, A. Lu, J.M. Feng and R. Huang: Mater. Lett. 56(5) (2002), p.756.

Google Scholar

[18] R.J.T. Lin, D. Bhattacharyya and S. Fakirov: accepted for publication in the Intl. J. Mod. Phys. - B (2006).

Google Scholar

[19] K.L. Leung1, A. Easteal and D. Bhattacharyya: paper No. 215-N, the 5th Asian-Australasian Conference on Composite Materials (ACCM-5), Hong Kong, China, 27-30 November (2006).

Google Scholar