Air Plasma Spraying of LSM/YSZ SOFC Composite Cathodes

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Abstract:

Porous composite cathodes containing (La0.8Sr0.2)0.98MnO3 (LSM) and yttria stabilized zirconia (YSZ) for use in solid oxide fuel cells (SOFCs) have been produced by air plasma spraying. Deposition was carried out using axial powder injection for increased deposition efficiency and composition control. A number of composite cathodes were produced using different combinations of parameter values within the identified range. Successful coatings were then characterized for composition and porosity using EDX and SEM. As a result of these tests, combinations of input parameter values were identified that are best suited to the production of coatings with microstructures appropriate for use in SOFC composite cathodes.

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Periodical:

Advanced Materials Research (Volumes 15-17)

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299-304

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February 2006

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. de Souza, S.J. Visco and L.C. De Jonghe, Thin-film solid oxide fuel cell with high performance at low temperature, Solid State Ionics , Vol 98, Nos. 1-2 (1997), pp.57-61.

DOI: 10.1016/s0167-2738(96)00525-5

Google Scholar

[2] A. Barbucci, R. Bozzo, G. Cerisola, P. Costamagna, Characterisation of composite SOFC cathodes using electrochemical impedance spectroscopy. Analysis of Pt/YSZ and LSM/YSZ electrodes, Electrochimica Acta, 47 (2002), pp.2183-2188.

DOI: 10.1016/s0013-4686(02)00095-6

Google Scholar

[3] M.J.L. Ostergard, C. Clausen, C. Bagger and M. Mogensen, Manganite-Zirconia Composite Cathodes for SOFC: Influence of Structure and Composition, Electrochim Acta., Vol 40, No. 12 (1995), p.1971-(1981).

DOI: 10.1016/0013-4686(94)00332-u

Google Scholar

[4] D. Stöver, H. Buchkremer and S. Uhlenbruck, Processing and properties of the ceramic conductive multilayer device solid oxide fuel cell (SOFC), Ceramics International, Vol. 30, No. 7 (2004), pp.1107-1113.

DOI: 10.1016/j.ceramint.2003.12.018

Google Scholar

[5] G. Schiller, R. Henne, M. Lang and M. Muller, Development of Solid Oxide Fuel Cells (SOFC) for Stationary and Mobile Applications by Applying Plasma Deposition Processes", Proceedings of Thermec, 2003: International Conference on Processing & Manufacturing of Advanced Materials (2004).

DOI: 10.4028/www.scientific.net/msf.426-432.2539

Google Scholar

[6] K. Barthel and S. Rambert, Thermal Spraying and Performance of Graded Composite Cathodes as SOFC-Component, Proceedings of the 5th International Symposium on Functionally Graded Materials (1998), pp.800-805.

DOI: 10.4028/www.scientific.net/msf.308-311.800

Google Scholar

[7] M. Lang, T. Franco, G. Schiller and N. Wagner, Electrochemical characterization of vacuum plasma sprayed thin-film solid oxide fuel cells (SOFC) for reduced operating temperatures, J. Appl. Electrochem., Vol 32, No. 8 (2002), pp.871-874.

DOI: 10.1016/s1464-2859(00)88860-4

Google Scholar

[8] R. Zheng, X.M. Zhou, S.R. Wang, T. -L. Wen and C.X. Ding, A Study of Ni+8YSZ/8YSZ/La0. 6Sro. 4CoO3-δ ITSOFC fabricated by atmospheric plasma spraying, J. Power Sources, Vol 140, No. 2 (2005), pp.217-225.

DOI: 10.1016/j.jpowsour.2004.06.015

Google Scholar

[9] B.D. White, O. Kesler, N. Ben-Oved, A. Burgess, Preparation of an SOFC LSM/YSZ Composite Cathode by Air Plasma Spraying, to be published in the Proceedings of the International Thermal Spray Conference and Exposition (ISTC) (2006).

DOI: 10.31399/asm.cp.itsc2006p0827

Google Scholar

[10] K. Barthel, and S. Rambert, Processing and Electrochemical Behaviour of LSM-YSZ Composite Cathodes by Vacuum Plasma Spraying, Proceedings of the 3 rd European Solid Oxide Fuel Cells Forum (1998), pp.11-18.

Google Scholar