Improved Adhesion to ABS Plastics by a Photocatalytic Reaction

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Abstract:

The pretreatment of ABS (acrylonitrile-butadiene-styrene) plastics prior to metallization has been generally performed with strong acids, such as sulfuric, chromic, or potassium-permanganate acid. However, conventional wet-chemical pretreatment presents inherent environmental and safety problems to consider. In particular, the presence of Cr+6 imposes a serious environmental threat. Therefore, in this study, aspects of pretreatment, using the photocatalytic reaction in TiO2 sol, were investigated as a replacement for wet-chemical pretreatment. Surface characterization, before and after the pretreatment, was examined by X-ray photoelectron spectroscopy and scanning electron microscopy. A copper film was deposited by electroless plating, and the adhesion strength between the deposited film and ABS plastics was evaluated by the cross-cut tape test (ISO 2409). When ABS plastics were pre-treated in TiO2 sol, the adhesion strength was improved to levels obtained using a strong acid solution.

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Periodical:

Materials Science Forum (Volumes 544-545)

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75-78

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May 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] GE Corp., Metallization Guide, GE Plastics, (1995).

Google Scholar

[2] I. K. Konstaninou, T. A. Albanis, Applied Catalalysis B: Environmental, 49 (2004) 1.

Google Scholar

[3] Akihiko Kudo, Catalysis Surveys from Asia, Vol. 7, No. 1, April (2003) 31-8.

Google Scholar

[4] K. L. Mittal and A. Pizzi, Adhesion promotion techniques: technological applications, Marcel Dekker, New York, (1999).

Google Scholar

[5] S. J. Kim, Materials Letters, Volume 60, Issue 3, (February 2006) 364-367.

Google Scholar

[6] N. V. Mandich, G. A. Krulik, On the mechanisms of plating on plastics, Plat. Surf. Finish. (December) (1993) 68-73.

Google Scholar

[7] I. Mathieson and R. H. Bradley, Int. J. Adhes. Adhes. 16 (1996) 29-31.

Google Scholar