Effect of Si on As-Cast Microstructure in Quasicrystalline Al-Cu -Fe Alloy

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Abstract:

Effect of Si on the forming ability of quasicrystalline phase in Al65Cu20Fe15 alloys fabricated under conventional casting conditions has been studied using X-ray diffraction (XRD), optical microscopy (OM), and scanning electron microscopy (SEM). The results show that under the conventional casting conditions, it is found that the addition of certain amount of Si into the Al-Cu-Fe melts can change the formation of Al62.5Cu25Fe12.5 quasicrystals during the solidification process. Compared with Al65Cu20Fe15 alloy, Al64.5Cu20Fe15Si0.5 alloy has smaller volume fraction of β phase solidifying initially, larger volume fraction of the quasicrystal phase generating in the subsequent peritectic reaction, and larger volume fraction of ω phase solidifying finally. Both experimental results and the theory of Hume-Rothery show that addition of Si can promote the formation ability of the icosahedral quasicrystalline Al62.5Cu25Fe12.5 phase in Al-Cu-Fe alloy.

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Materials Science Forum (Volumes 546-549)

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619-622

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May 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] LI Zhi-qiang, XU Zhou, LI Xiao-ping, WANG Shuo, Materials Review, 2002, 16(2): 9-11.

Google Scholar

[2] TSAI A P, AKIHISA I, TSUYOSHI M, Journal of Materials Science letters, 1987, 6(12): 1403-1405.

Google Scholar

[3] ELINA H S, Journal of Alloys and Compounds, 2004, 363(1-2): 150-174.

Google Scholar

[4] MURTY B S, BARUA P, SRINIVAS V, SCHURACK F, ECKERT J, J. Non-crystal. Solids, 2004, 334-335: 44-47.

DOI: 10.1016/j.jnoncrysol.2003.11.010

Google Scholar

[5] CHANG H J, FLEURY E, SONG G S, KIM WT, KIM D H, J. Non-Crystal. Solids, 2004, 334-335: 12-16.

Google Scholar

[6] SONG G S, LEE M H, KIM WT, KIM D H., J. Non-Crystal. Solids, 2002, 297(2-3): 254-262.

Google Scholar

[7] LEE S M, KIM B H, KIM S H, FLEURY E, KIM W T, KIM D H., Materials Science and Engineering, 2000, 294-296: 93-98.

Google Scholar

[8] MUKHOPADHYAY N K, KURUP V, SRIVASTAVA V C, JOSHI P B, MANDAL R K., J. Non-Crystal. Solids 2004, 334&335: 52-56.

DOI: 10.1016/j.jnoncrysol.2003.11.012

Google Scholar

[9] ELINA H S, TUOMO T, Materials Chemistry and Physics 2004, 85(2-3): 383-395.

Google Scholar

[10] ROUXEL D., GIL-GAVATZ M., PIGEAT P, WEBER B, J. Non-Crystal. Solids, 2005, 351(10-11): 802-809.

DOI: 10.1016/j.jnoncrysol.2005.02.013

Google Scholar

[11] CHEUNG Y L, CHAN K C, ZHU Y H., Materials Characterization 2001, 47(3-4): 299-305.

Google Scholar

[12] ZHAO Dong-shan, QU Wen-bang, WANG Ren-hui , SHEN Ning-fu, Shi Guang-xin, GUI Jia-nian, Acta Metallurgica Sinica , 2004�40 (1): 14-19.

Google Scholar

[13] ZHAO Dong-shan, GUO Xin-yong, SHEN Ning-fu, GUO Jian, REN Chen-xing, The Chinese Journal of Nonferrous Metals. 2004, 14 (5): 786-790.

Google Scholar

[14] DONG Chuang, Scripta Metallweica et Materialia, 1995, 33(2): 239-243.

Google Scholar

[15] DONG Chuang, Chinese Journal of Materials Research, 1994, 8(6): 481-490.

Google Scholar