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Intermediates in Ring-Disc Electrode Processes

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Abstract:

In the history of electrode processes, intermediates are of extraordinary interest. In the lecture which follows, the most common types of intermediates in electrode processes are classified. Secondly, most of the methods which are available and have been used in finding intermediates are characterised. Thirdly, the principles of detection of intermediate and final products of electrode processes on the basis of kinetic information obtained by means of the rotating ring-disc electrode method are discussed. This approach is used for identification of the products of an organic electroreduction. In conclusion, it is demonstrated that the cathodic reduction of such organic compounds involves formation of stable and unstable intermediates.

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Periodical:

Materials Science Forum (Volume 553)

Pages:

152-163

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.553.152

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Online since:

August 2007

Authors:

César A.C. Sequeira

Keywords:

Electrode Processes, Intermediate, Organic Electroreduction, Rotating Ring-Disc Electrode

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] J. Tafel: Z. Phys. Chem. Vol. 34 (1900), p.199.

Google Scholar

[2] J. Tafel: Z. Phys. Chem. Vol. 50 (1904), p.641.

Google Scholar

[3] K.J. Vetter: Z. Phys. Chem. Vol. 194 (1950), p.284.

Google Scholar

[4] K.J. Vetter: Z. Elektrochem. Vol. 55 (1951), p.121.

Google Scholar

[5] R. Parsons: Trans. Faraday Soc. Vol. 47 (1951), p.1332.

Google Scholar

[6] H. Gerischer: Z. Elektrochem. Vol. 57 (1953), p.604.

Google Scholar

[7] H. Gerischer: Z. Phys. Chem. Vol. 202 (1953), p.292.

Google Scholar

[8] H. Gerischer and K.J. Vetter: Z. Phys. Chem. Vol. 197 (1951), p.92.

Google Scholar

[9] M. LeBlanc and K. Schick: Z. Phys. Chem. Vol. 46 (1903), p.213.

Google Scholar

[10] M. LeBlanc and K. Schick: Z. Elektrochem. Vol. 9 (1903), p.636.

Google Scholar

[11] P. Dolin and B. Ershler: Acta Physicochim. U.R.S.S. Vol. 13 (1940), p.747.

Google Scholar

[12] B. Ershler: Disc Faraday Soc. Vol. 1 (1947), p.269.

Google Scholar

[13] J.E.B. Randles: Disc Faraday Soc. Vol. 1 (1947), p.11.

Google Scholar

[14] Z. Nagy, N.C. Hung, K.C. Liddell, M. Minkoff and G.K. Leaf: J. Electroanal. Chem. Vol. 421 (1997), p.33.

Google Scholar

[15] O.A. Kopistka and S.E. Batyrbekova: J. Electroanal. Chem. Vol. 336 (1992), p.223.

Google Scholar

[16] Z. Nagy, M. Minkoff, G.K. Leaf and R.H. Land: Electrochim. Acta Vol. 32 (1987), p.1777.

Google Scholar

[17] H. Gerischer and W. Vielstich: Z. Phys. Chem. (Frankfurt) Vol. 3 (1955), p.16.

Google Scholar

[18] A. Weissberger, ed.: Techniques of Organic Chemistry VIII-2 (Interscience, New York 1963).

Google Scholar

[19] A.N. Frumkin and L.N. Nekrasov: Dokl. Akad. Nauk S.S.S.R. Vol. 126 (1959), p.115.

Google Scholar

[20] A. Frumkin, L. Nekrasov, B. Levich, and Y. Ivanov: J. Electroanal. Chem. Vol. 1 (1959), p.84.

Google Scholar

[21] D. Sopchak, B. Miller, Y. Avyigal and R. Kalish: J. Electroanal. Chem. Vol. 538-539 (2002), p.34.

Google Scholar

[22] C.A.C. Sequeira, N.R. Sousa, R.P.C. Neto and G. Anastassakis: Recycling and Waste Treatment in Mineral and Metal Processing Vol. 1, p.663 (T.M.S., Warrendale, USA 2002).

Google Scholar

[23] C.A.C. Sequeira, D.M.F. Santos and W. Baptista: Proc. 1 st Int. Conf. on Diffusion of Solids and Liquids, DSL-2005 Vol. II, p.659 (Univ. of Aveiro, Portugal 2005).

Google Scholar

[24] R. Cai, S. Song, B. Ji, W. Yang, Q. Xin, G. Sun, S. Douvartizdes and P. Tsiakaras: Applied Catalysis B: Environmental Vol. 61 (2005), p.184.

Google Scholar

[25] K.E. Heusler and H. Schurig: Z. Phys. Chem. (Frankfurt) Vol. 47 (1965), p.117.

Google Scholar

[26] H. Gerischer, I. Mattes and R. Braun: J. Electroanal. Chem. Vol. 10 (1965), p.553.

Google Scholar

[27] M. Cardona: Modulation Spectroscopy (Academic Press, New York 1969).

Google Scholar

[28] T. Kuwana: Ber. Bunsenges Phys. Chem. Vol. 77 (1973), p.751.

Google Scholar

[29] R.W. Murray, W.R. Heinemann and G.W. O'Dorn: Anal. Chem. Vol. 39 (1967), p.1666.

Google Scholar

[30] M. Caravati, D.M. Meier, J. -D. Grunwaldt and A. Baike: J. Catalysis Vol. 240 (2006), p.126.

Google Scholar

[31] K.J.J. Mayrhofer, M. Arenz, B.B. Blizanac, V. Stamenkovic, P.N. Ross and N.M. Markovic: Electrochim. Acta Vol. 50 (2005), p.5144.

DOI: 10.1016/j.electacta.2005.02.070

Google Scholar

[32] W.N. Hansen: Adv. Electrochem. Electrochem. Eng. Vol. 9 (1973), p.10.

Google Scholar

[33] P.A. Brooksby and W.R. Fawcett: Spectrochim. Acta A: Mol. & Biomol. Spectroscopy Vol. 64 (2006) p.372.

Google Scholar

[34] U. Wolf, R. Lieberich and J. Seeba: Catalysis Today Vol. 49 (1999), p.411.

Google Scholar

[35] M.H. Shao and R.R. Adzic: Electrochim. Acta Vol. 50 (2005), p.2415.

Google Scholar

[36] J.D.E. McIntyre: Adv. Electrochem. Electrochem. Eng. Vol. 9 (1973), p.61.

Google Scholar

[37] D.M. Kolb: Ber. Bunsenges Phys. Chem. Vol. 77 (1973), p.891.

Google Scholar

[38] Ph. Lambin, L. Henrard, P. Thiry, C. Silien and J.P. Vigneron: J. Electron. Spectroscopy & Related Phen. Vol. 129 (2003), p.28.

DOI: 10.1016/s0368-2048(03)00079-3

Google Scholar

[39] D.H. Geske and A.H. Maki: J. Am. Chem. Soc. Vol. 82 (1960), p.2671.

Google Scholar

[40] R. Koopmann and H. Gerischer: Ber. Bunsenges Phys. Chem. Vol. 70 (1966), p.118, 127.

Google Scholar

[41] S.A. Cheng, W. -K. Fung, K. Yu Chan and P.K. Shen: Chemosphere Vol. 52 (2003), p.1797.

Google Scholar

[42] W.S. Szulbinski: Spectrochim. Acta A: Mol. & Biomol. Spectroscopy Vol. 56 (2000) 357.

Google Scholar

[43] J. Malyszko, E. Malyszko, E. Ferchichi and M. Kaczor: Anal. Chim. Acta Vol. 376 (1998) 357.

Google Scholar

[44] B. Merzougui, Y. Berchadsky, P. Tordo and G. Gronchi: Electrochim. Acta Vol. 42 (1997) 2445.

DOI: 10.1016/s0013-4686(96)00427-6

Google Scholar

[45] W.J. Albery and S. Bruckenstein: Trans. Faraday Soc. Vol. 62 (1966), p. (1946).

Google Scholar

[46] D.T. Napp, D.C. Johnson and S. Bruckenstein: Anal. Chem. Vol. 39 (1967), p.481.

Google Scholar

[47] S. Bruckenstein: Elektrokhim. Vol. 2 (1966), p.1085.

Google Scholar

[48] W.L. Davis, R.F. Shago, E.H.G. Langner and J.C. Swarts: Polyhedron Vol. 24 (2005) 1611.

Google Scholar