Application of Mesophilic Mixed Micro-Organisms for Recovery of Valuable Metals from Spent Refinery Catalysts

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Abstract:

Bioleaching of pre-treated spent refinery catalyst was performed using sulfur and iron oxidizing bacteria separately. Both the mixed cultures were grown at various concentration of either ferrous sulfate or elemental sulfur. Bioleaching process was conducted by varying the reaction time, effect of substrates and effect of catalyst amount. Under the most favourable transport conditions examined, (5g/L spent catalysts, 10g/L ferrous sulfate, reaction time 7 days) the mixed iron oxidizing bacteria were able to recover Ni, V, and Mo of 90, 80 and 54 % respectively. Higher catalyst and ferrous sulfate concentration showed decline result in recovery of Mo and V. Ni showed consistent results throughout the series of experiments (88 to 90% recovery). The mixed sulfur oxidizing bacteria were observed to be more effective than the iron oxidizing bacteria. The sulfur oxidizing cells were able to recover Ni, V and Mo of 88, 94 and 46 % respectively (spent catalysts 50g/L, elemental sulfur of 2% (w/v), reaction time 7 days). The oxidation of elemental sulfur to sulfate could play a vital role for extraction of the metals.

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Advanced Materials Research (Volumes 20-21)

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119-125

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July 2007

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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[1] Aung, K.M.M., Ting Y.P., 2005. Bioleaching of spent fluid catalytic cracking catalyst using Aspergillus niger. Journal of Biotechnology 116, 159-170.

DOI: 10.1016/j.jbiotec.2004.10.008

Google Scholar

[2] Santhiya, D., Ting Y.P., 2005. Bioleaching of spent refinery processing catalyst using Aspergillus niger with high-yield oxalic acid. Journal of Biotechnology 116, 171-184.

DOI: 10.1016/j.jbiotec.2004.10.011

Google Scholar

[3] Pourbaix M., Atlas of Electrochermical equilibria in aqueous solutions. National Association of Corrosion Engineers, Houston, Texas. (1974).

Google Scholar

[4] Staley, J.T., Bryant, M.P., Pfenning, N., Holt, J.G., (Eds. ), 1989. Bergey's Manual of Systematic Bacteriology. Vol 3, Williams and Wilkins, USA, p.1857.

Google Scholar

[5] Harrison A.P., The acidophilic thiobacilli and other acidophilic bacteria that share their habitat, Annu Rev Microbiol 38 (1984) 265-292.

DOI: 10.1146/annurev.mi.38.100184.001405

Google Scholar

[6] Trimm, D., The Regeneration or disposal of deactivated heterogeneous catalysts. Applied Catalysis, 212 (2001) 153-160.

DOI: 10.1016/s0926-860x(00)00852-8

Google Scholar

[7] Yoo, J., Metal recovery and rejuvenation of metal loaded spent catalysts. Catalysis Today, 44 (1998) 27-46.

DOI: 10.1016/s0920-5861(98)00171-0

Google Scholar