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Phase Transformations in the Metallic Materials Being Electrodeposited and their Application for the Development of Advanced Technologies for Anticorrosive Protection of Canned-Food Steel Sheet

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Abstract:

It has been found that during the electrodeposition of metallic material a supercooled metallic liquid is being formed that is solidified at the deposition temperature in the form of a crystalline or amorphous phase. These phase transformations are proved by the existence in the electrodeposited metals of metastable structures that correspond to: the amorphous structure of the solidified metallic liquid, the highly defective crystalline structure of the metal quenched from the liquid state, and the intermediate modifications that had appeared during the fast crystallization of the liquid phase of the polymorphous metal. On the basis of this phenomenon there have been developed the technologies for producing of protective texturally-composite tin electrocoat, nanostructurally-texturally-composite chromium electrocoat, and amorphous composite chromium electrocoat on canned-food steel sheet.

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Periodical:

Materials Science Forum (Volumes 561-565)

Pages:

2369-2372

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.561-565.2369

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Online since:

October 2007

Authors:

Oleg Girin

Keywords:

Amorphous Structure, Canned-Food Steel Sheet, Electrochemical Deposition, Electrocoating, Metallic Liquids, Metallic Material, Nanostructure, Structure Formation, Texture

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© 2007 Trans Tech Publications Ltd. All Rights Reserved

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References

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[4] O.B. Girin, in: Materials Development and Processing, edited by J.V. Wood, L. Schultz and D.M. Herlach, WILEY-VCH Verlag Gmbh, Weinheim, Germany (2000), p.189.

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