New Polymeric Binders in Ceramic Processing

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Abstract:

The results of studies on the application of new water-dispersible binders such as poly(acrylic-styrene), poly(acrylic-allyl ether) for die and isostatic pressing and tape casting of Al2O3 ceramics are presented. The properties of these acrylic polymers were modified by insertion of selected amphiphilic macromonomers into the polymer chains. These amphiphilic macromonomers, due to the proper ratio of the hydrophilic to hydrophobic fragments, play the role of not only an internal plasticizer, but they also modify the adhesion of such binders to the ceramic powder particles. The influence of chemical structure of these copolymers on the properties of alumina ceramics is discussed. The investigations on properties of alumina ceramics obtained by gelcasting method using new water soluble acrylic monomers containing hydroxyl groups in their chemical structure as well as by direct coagulation casting method using polymeric flocculants are also presented and discussed.

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453-461

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October 2006

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© 2006 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Szafran, Z. Florjańczyk, G. Rokicki, E. Zygadło-Monikowska and N. Langwald: in 9th CIMTEC - World Ceramics Congress and on New Materials (Florence, June 1998), Ceramics: Getting into the 2000's - Part B. P. Vincenzini (Ed. ), Techna Srl, Florence, Italy, 1999, p.515.

Google Scholar

[2] M. Szafran, G. Rokicki: J. Am. Ceram. Soc. Vol. 84 (2001), p.1231.

Google Scholar

[3] P. Wiśniewski, M. Szafran, G. Rokicki: Key Engineering Materials Vol. 264-268 (2004), p.125.

Google Scholar

[4] W. Huismann, T.J. Graule, L.J. Gauckler: J. Am. Ceram. Soc. Vol. 51 (1995), p.451.

Google Scholar

[5] M. Szafran, K. Jach, A. Tomaszewska-Grzęda, G. Rokicki: CIMTEC 2002-10th International Ceramic Congress and 3rd Forum on New Materials, 10th International Ceramic Congress-Part A, P. Vincencini (Ed. ), Techna Srl, Florence, Italy, 2003, p.667.

DOI: 10.1515/ci.2001.23.5.155a

Google Scholar

[6] M. Szafran, K. Jach, A. Tomaszewska-Grzęda: Key Engineering Materials Vol. 264-268 (2004), p.69.

Google Scholar

[7] M.A. Janney, US Patent 4 894 194 (1990).

Google Scholar

[8] O.O. Omatete, M.A. Janney, S. Nunn: J. Eur. Ceram. Soc. Vol. 17 (1997), p.407.

Google Scholar

[9] J. Stampfl, H.C. Liu, S.W. Nam, K. Sakamoto, H. Tsuru, S. Kang, A.G. Cooper, A. Nickel, F.B. Prinz: Mater. Sci. Eng. Vol. A334 (2002), p.187.

Google Scholar

[10] J. Ma, Z. Yi, Z. Xie, L. Zhou, H. Miao, B. Zhang, X. Lin Ceram. Int. Vol. 31 (2005), p.1015.

Google Scholar

[11] K. Cai, Y. Huang, J. Yang, J. Europ. Ceram. Soc. Vol. 25 (2005), p.1089.

Google Scholar

[12] C. Tallon, D. Jach, R. Moreno, M.I. Nieto, G. Rokicki, M. Szafran: Proceedings of the 3rd International Conference on Shaping of Advanced Ceramics, Limoges, France, May 10, (2006).

Google Scholar