Paper Title:
Preparation, Characterization and Thermal Behavior of Copper(II) Complex with 1-(6-Hydroxynaphthalen-2-Yl)butane-1,3-Dione
  Abstract

A complex of Cu(II) with 1-(6-hydroxynaphthalen-2-yl) butane-1,3-dione (HNBD) was synthesized and characterized by elemental analysis, IR, UV and TG-DTA techniques. IR spectra as well as UV-visible absorption measurements indicated that Cu(II) ion was coordinated to the HNBD ligand. The TG-DTA curves showed that the thermal decomposition for Cu(II) complex was a three-steps process. At first, the complex had a mass loss of water molecules at temperature below 134°C, then the thermal decomposition of the anhydrous complex was a two-stage process, which corresponded to the loss of two naphthol molecules and the oxidative decomposition of other organic fragments of ligand. The final decomposition product of the complex was CuO.

  Info
Periodical
Chapter
Chapter 7: Functional Materials
Edited by
Huixuan Zhang, Ye Han, Fuxiao Chen and Jiuba Wen
Pages
1370-1373
DOI
10.4028/www.scientific.net/AMM.117-119.1370
Citation
D. J. Wang, B. P. Xu, Y. F. Kang, "Preparation, Characterization and Thermal Behavior of Copper(II) Complex with 1-(6-Hydroxynaphthalen-2-Yl)butane-1,3-Dione", Applied Mechanics and Materials, Vols. 117-119, pp. 1370-1373, 2012
Online since
October 2011
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$32.00
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