After several decades of research, the traditional modeling methods, such as geometric model，feature model and integrated product model, can’t fully meet the integrated product information and the related knowledge that required. Meanwhile, lack of semantics, is not conducive to the using and sharing of knowledge. Semantic-based product design and process decision can shorten the product development cycle, reduce costs and allow the computer to participate in the design. Based on building of complex electronic products ontology and already been built OWL ontology file introduced into database, this paper combines Ontology model of complex electronic products with the semantic Web, studies a network design model based on the semantic Web and develops a product design and process decision Web platform based on semantic. The platform can realize product design, semantic search of the resources and decision of parts machining process, thus, to improve the productivity and enhance the efficiency and competitiveness of the company by the system.