Paper Title:
Preparation of Ternary Rare Earth Sulfide LnxGd2-xS3 (Ln: La, Tb)
  Abstract

We investigated the formation behavior of ternary rare earth sulfide LnxGd2-xS3 (Ln: La, Tb). Ternary rare earth sulfide LnxGd2-xS3 (Ln: La, Tb) was synthesized via the sulfurization of their commercial oxide powders using CS2 gas for short sulfurization time. It was found that ternary rare earth sulfide LnxGd2-xS3 (Ln: La, Tb) could be synthesized for a short sulfurization time of 3 h at 1100°C. For LaxGd2-xS3, it crystallizes in α phase (Orthorhombic phase), the crystal structure is different from rare earth sulfide La10S14-xOx which crystallizes in β phase (Tetragonal phase) but is same with rare earth sulfide α-Gd2S3. TbxGd2-xS3 also crystallizes in α phase, the crystal structure is same with rare earth sulfide α-Tb2S3.

  Info
Periodical
Advanced Materials Research (Volumes 105-106)
Edited by
Wei Pan and Jianghong Gong
Pages
812-814
DOI
10.4028/www.scientific.net/AMR.105-106.812
Citation
H. B. Yuan, W. X. Yi, "Preparation of Ternary Rare Earth Sulfide LnxGd2-xS3 (Ln: La, Tb)", Advanced Materials Research, Vols. 105-106, pp. 812-814, 2010
Online since
April 2010
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$32.00
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