Paper Title:
Novel Porous 3D Network Structure Formed by Self-Assembly of Tetrakis(phthalimide) Palladium(II) Complex
  Abstract

A disodium tetrakis(phthalimide) palladium(II) complex, [Na2Pd(phthal)4] (1), was synthesized by reaction of four phthalimide molecules with Pd(OAc)2 in the presence of Et3N. The above and below axial sites of the Pd coordination plane formed the spaces suitable for capturing Na+ ions, which were coordinated with the four imidato oxygen atoms. The complex 1 was linked through the Na+ ions bridged by the water molecules, building an infinite chain structure along the crystallographic a axis. The four phthalimidato moieties contacted in the four orthogonal directions together through their π-π stacking interaction. Such a self-assembly of molecule 1 constructed nanopores with a pore size of ca. 3 × 4 Å in the crystals.

  Info
Periodical
Advanced Materials Research (Volumes 11-12)
Main Theme
Edited by
Masayuki Nogami, Riguang Jin, Toshihiro Kasuga and Wantai Yang
Pages
473-476
DOI
10.4028/www.scientific.net/AMR.11-12.473
Citation
N. Ichieda, T. Kamimura, S. Yamaguchi, Y. Funahashi, T. Ozawa, K. Jitsukawa, H. Masuda, "Novel Porous 3D Network Structure Formed by Self-Assembly of Tetrakis(phthalimide) Palladium(II) Complex", Advanced Materials Research, Vols. 11-12, pp. 473-476, 2006
Online since
February 2006
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$32.00
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