Aiming at current environmental condition of energy shortage and excessive emission, this paper presents the development of solar energy clothing on human comfort. In this clothing, solar flexible materials are made into appropriate part of garment. In ensuring the comfort of human, this garment can accumulate solar energy, safely output stable current. So this clothing has the function of providing power. After a number of experiments and analysis, this clothing is proved that it has convenient, practical, favorable environment, and comfort for human.