The reutilization of waste Printed Circuit Boards (PCB) is a focused topic in the field of environment protection and resource recycling, and the crushing is the crucial process for recycling waste PCB. A hamper impacting crusher was used to achieve metals crushing liberation from non-metals, the liberation mechanism of PCB can be explained by dispersion liberation accompanied disengaging liberation. The Rosin-Rammler distribution model of crushed PCB particle was put forward. The evaluation indexes show that Rosin-Rammler function can accurately describe size distribution of PCB particles because the convergence property R2 is 0.99694 and fitting error E is 4.80658. The selective crushing is appearance with metals concentrated in coarser fraction and non-metals in finer size during comminution processing. The impact crushing is an effective method to metals liberation of PCB particles.