Paper Title:
Synthesis and Characterization of Nanocomposites Based on Copolymers of POSS-ONDI Macromonomer and TFONDI: Effect of POSS on Thermal, Microstructure and Morphological Properties.
  Abstract

Polyhedral oligomeric silsesquioxanes (POSS) possessing 7-oxanorbornene-5, 6-dicarboximide (POSS-ONDI) functionalized macromers are synthesised and well characterized using FT-IR, 1H, 13C and 29Si-NMR spectroscopic techniques. The homopolymer of [N-3(trifluoromethyl)phenyl-7-oxanorbornene-5,6-dicarboximide] (TFONDI) and a series of linear copolymers between [N-(POSS)-7-oxanorbornene-5, 6-dicarboximide] POSS-ONDI and TFONDI are prepared through ring opening metathesis polymerisation (ROMP) using Grubbs catalyst. All the polymers are characterized using FT-IR, 1H-NMR, TGA, DSC, AFM, TEM, XRD and GPC techniques.

  Info
Periodical
Advanced Materials Research (Volumes 123-125)
Edited by
Joong Hee Lee
Pages
775-778
DOI
10.4028/www.scientific.net/AMR.123-125.775
Citation
D. Gnanasekaran, B.S.R. Reddy, "Synthesis and Characterization of Nanocomposites Based on Copolymers of POSS-ONDI Macromonomer and TFONDI: Effect of POSS on Thermal, Microstructure and Morphological Properties.", Advanced Materials Research, Vols. 123-125, pp. 775-778, 2010
Online since
August 2010
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