Paper Title:
Alkylation of Benzene with Propylene over H3PW12O40 Supported on MCM-41 and -48 Type Mesoporous Materials
  Abstract

The present work, the HPA Keggin structure was supported on four different MCM phase types (hexagonal, spherical, elliptical, and cubic); their catalytic properties were tested in the alkylation of benzene with propylene in order to produce cumene. In the reaction, parameters like propylene flow, reaction temperature, phase type, as well as WHSV-1, HPA, and Cs content in the best MCM phase support were studied. The results showed that the MCM-48 with (30 wt. % HPA) catalyst had the best behavior in catalytic activity, showing the higher conversion and selectivity toward cumene as the main product.

  Info
Periodical
Edited by
Jin-An Wang, Guozhong Cao and José Manuel Domínguez
Pages
192-204
DOI
10.4028/www.scientific.net/AMR.132.192
Citation
M. Gómez-Ruiz, J. A. Melo-Banda, C.E. Ramos Galván, S.E. López, R.R. Silva, R.I. Alamilla, J.M. Domínguez, "Alkylation of Benzene with Propylene over H3PW12O40 Supported on MCM-41 and -48 Type Mesoporous Materials", Advanced Materials Research, Vol. 132, pp. 192-204, 2010
Online since
August 2010
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Zhi Wei Guo, Ying Ying Gu, Shi Lin Zhou, Chen Hong Ren
Abstract:Phthalocyanine catalysts were synthesized and supported matel phthalocyanines were found to be good catalysts for benzene hydroxylation to...
1575
Authors: Jun Hui Li, Ya Nan Wang, Jun He, Zhi Rong Zhu
Chapter 9: Energy Chemical Engineering
Abstract:Alkylation of benzene with ethanol for synthesis of ethylbenzene was performed over parent zeolites and zeolites modified with La2O3, such as...
3670
Authors: Er Qiang Wang, Cheng Yue Li, Lang You Wen, Ze Xue Du, Yong Qiang Zhang
Chapter 13: Modeling, Simulation and Emulation
Abstract:This paper deals with alkylation of benzene with propylene to produce cumene by Suspension Catalytic Distillation (SCD) which, as a new...
2243
Authors: Fei Zhao, Yu Zhang, Shu Dong Geng, Lian Fa Chen, Wei Wang
Chapter 1: Chemical Engineering
Abstract:MCM-22 “family” zeolites (MCM-22, MCM-49 and MCM-56) have been synthesized hydrothermally by dynamic method. All materials were characterized...
283
Authors: Caroline Vasconcelos Fernandes, Vitória de Andrade Freire, Bianca Viana de Sousa
Chapter 1: Synthesis of Powder and Porous Materials
Abstract:MCM-22 is a microporous molecular sieve with a system of sinusoidal three-dimensional channels that do not interconnect themselves, which...
41