Paper Title:
The Synthesis and Properties of a Novel Solid Polyphosphazene Electrolyte for Lithium Ion Battery
  Abstract

Polydichlorophosphazene was synthesized from hexachlorocyclotriphosphazene by high-temperature ring-opening polymerization, and poly(2-(2-methoxyethoxy) ethanol phosphazene)(MEEP) was synthesized by reacting polydichlorophosphazene with alcohol sodium. The optimal synthesis parameters were obtained and the structure of MEEP was analyzed by NMR. Then polyphosphazene electrolyte was prepared by mixing MEEP with LiCF3SO3. The results indicated that the electrolyte prepared in this paper has high decomposition temperature, and its room-temperature conductivity is up to 1.187×10-4 S/cm.

  Info
Periodical
Advanced Materials Research (Volumes 148-149)
Edited by
Xianghua Liu, Zhengyi Jiang and Jingtao Han
Pages
749-752
DOI
10.4028/www.scientific.net/AMR.148-149.749
Citation
M. S. Yang, J. W. Liu, J. Yu, X. Zhang, J. Wei, L. K. Li, "The Synthesis and Properties of a Novel Solid Polyphosphazene Electrolyte for Lithium Ion Battery", Advanced Materials Research, Vols. 148-149, pp. 749-752, 2011
Online since
October 2010
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$32.00
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