This paper discussed the feasibility of unburned and non-autoclaved, steam cured bricks prepared by FGD byproducts from coal-fired power plants. The results show that FGD byproduct, aggregates, cementious materials and water could be used to prepare bricks during the process of stir and compaction under natural cure and steam cured condition. S4 and Z2 are the optimum design mixture composition. The maximum compressive strength and saturation coefficient are 28.7 MPa and 96.7%. FGD byproducts do no harm to environment and a pilot-scale experiment demonstrates that bricks made with FGDA can meet the MU10 level bricks technical requirement.