Pseuado Zn-Al alloy coatings were made by using of dissimilar metal wire arc spraying technology on the surface of the steel Q235 and the H2S corrosion experiment was carried out on the coatings. The corrosion rate was calculated with weight-loss method. The configurations of Zn-Al coatings before and later suffered corrosion were observed with scanning electron microscope, and the coating surfaces were analyzed with energy spectrum. The corrosion potential of the coatings was tested by using the electrochemistry testing system. The corrosion results showed that Zn-Al coatings can protect the covered steel surface and the steel substrate exposing in the corrosion environment. Being processed with pore sealer, the coatings have shown more excellent corrosion resistance.