CrZrCu is extensively used in spot welding due to their high electrical, thermal and mechanical performance. But when CrZrCu electrode is used in spot welding of galvanized steel sheet, the abrasion, corrosion and oxidation shorten the electrode life rapidly. The electrode is not able to meet the needs of spot welding of galvanized steel sheet .In the paper, double glow plasma discharge surface titanizing was carried out on CrZrCu alloy. The processes of double glow plasma discharge titanizing, surface alloying layer structure were also analyzed elementary. The wear resistance property of glow discharge plasma titanizing layer was also researched. The experimental results indicated that in the plasma titanizing alloying layer, the diffusion of titanium element toward the interior of the CrZrCu alloy substrate forms the intermetallic compound named Cu4Ti, which is beneficial to the reinforcement of CrZrCu substrate. The experimental results confirmed that double glow plasma discharge titanizing could improve the wear resistance of CrZrCu alloy greatly. Under the external load of 300N and 500N, the wear resistance of double glow plasma discharge titanizing layer is7 times and 8.5 times than that of CrZrCu.