Al-8%Si alloy double-coating on Q235 steel were produced, Then the samples were executed diffusion at high temperatures protecting with flowing argon gas. Scanning electron microscope (SEM), optical microscope (OM), and energy dispersive X-ray spectroscope (EDS) were employed for microstructure observation of cross-sectional, surface and compositional analysis of coating. The diffusion mathematical model was established with the finite element method. The results show that good quality Al-8%Si coating is made; after heat-diffusion treatment, the new phases FeAl and Fe3Al presents; Silicon atoms in Al-8%Si alloy can hinder the diffusion of aluminum atoms into steel substrate at high temperature; Al-8%Si alloy double-coating sample’s high-temperature oxidation resistance is higher than Q235 steel. This material is hopefully used in the engine exhaust manifold.