The influence of frictional wear characteristics were investigated under the Self-repairing Additive condition with different concentration by using MMU-5G end-face friction and wear testing machine. The surface images of friction pair and their chemical composition were detected by using SEM and EDS. The result indicates different concentration has a great influence on frictional wear characteristics of friction pair. The Self-repair coatings are formed on the 45#steel worn surface while nothing on the cast-iron worn surface, study considers that metallographic structure and mechanical performance of cast iron are the prime causation resulting in no Self-repair coatings. Self-repairing Additive of the right concentration has remarkable effect on antifriction and wearing of cast iron.