In this paper, effect of pre-deformation and ageing on compressive behavior of Ti-58.25wt%Ni was investigated at room temperature. Through range analysis of three factors and three levels on transformation temperature measured by DSC, ageing at 673K enhanced phase transformation temperature obviously, the As temperature could reach 308.02K. Transformations of B2-B19’ and B2-R-B19’ appeared after the treatments. Saw tooth shape phenomenon on the loading curves indicating the typical martensitic transformation was also observed. Dynamic balance due to compatible action among various phase under increased load kept the slope of the loading curves constantly. Pre-deformation by 0.2% resulted in higher compressibility (4.9%), and ageing at 523K caused better recovery (95.4%).