Paper Title:

Reduced Graphene Sheets as Catalysts for Oxygen Reduction Reaction in Alkaline Media

Periodical Advanced Materials Research (Volumes 197 - 198)
Main Theme New and Advanced Materials
Edited by Huaiying Zhou, Tianlong Gu, Daoguo Yang, Zhengyi Jiang, Jianmin Zeng
Pages 667-671
DOI 10.4028/www.scientific.net/AMR.197-198.667
Citation Jia Jia Wu et al., 2011, Advanced Materials Research, 197-198, 667
Online since February, 2011
Authors Jia Jia Wu, Yi Wang, Dun Zhang
Keywords Catalysis, Kinetic, Oxygen Reduction Reaction, Reduced Graphene Sheets
Price US$ 28,-
Article Preview
View full size
Abstract

Reduced graphene sheets (RGSs) were prepared via hydrazine reduction of exfoliated graphite oxide and their morphology was characterized by atomic force microscopy. The electrocatalytic reduction of oxygen (O2) with RGSs was studied by cyclic and rotating risk electrode voltammetry using RGSs-modified glassy carbon electrodes in alkaline media. The results show that this modification with RGSs makes the peak potential shift in the positive direction and increases the peak current. The kinetics study shows that the numbers of electrons transferred for the oxygen reduction reaction are ca. 3 at potentials of the first reduction wave, indicating the peroxide produced can transfer into OH.