Paper Title:
Synthesis of Asymmetric Tridentate Cobalt(II) Complex and Application in Ethylene Oligomerization
  Abstract

A kind of cobalt complex with asymmetric tridentate ligand was synthesized and used in ethylene oligomerization. The reaction temperature and Al/Co ratio had a great influence on the activities and distributions of the oligomer with methylaluminoxane as cocatalyst, and the main products were 1-butylene and hexene. A fast deactivation process was observed from the curve of the oligomerization kinetics.

  Info
Periodical
Advanced Materials Research (Volumes 233-235)
Edited by
Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He
Pages
1540-1543
DOI
10.4028/www.scientific.net/AMR.233-235.1540
Citation
C. G. Cao, I. Y. Ahn, T. Jiang, "Synthesis of Asymmetric Tridentate Cobalt(II) Complex and Application in Ethylene Oligomerization", Advanced Materials Research, Vols. 233-235, pp. 1540-1543, 2011
Online since
May 2011
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