Paper Title:
Synthesis and Characterization of the Layered Zirconium Phosphate and its Intercalation Study
  Abstract

The zirconium phosphate α-Zr(HPO4)2·H2O (α-ZrP) with layered structure has been synthesized by refluxing method. Power X-ray diffraction (XRD), vibrational spectroscopy (FT-IR, FT-Raman), thermal analysis (TG-DSC), transition electron spectroscopy (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray spectrometer (EDS) was respectively used for structure characterization of the compound α-ZrP. The result of intercalation reactions with tetramethylammonium bromide and cetyltrimethylammonium bromide showed interlayer distances increase of ~ 0.46 nm and ~ 1.68 nm, respectively. The BET surface area of α-ZrP is 12.29 m2·g-1. The cyclic voltammetry behaviors of the compound on Au electrode showed a typical reversible process. Moreover, the strong fluorescent property of the α-ZrP was measured. The maximum emission peaks occurred at ca. 390 nm upon excitation at ca. 288 nm.

  Info
Periodical
Advanced Materials Research (Volumes 233-235)
Edited by
Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He
Pages
1809-1813
DOI
10.4028/www.scientific.net/AMR.233-235.1809
Citation
Y. P. Tong, C. L. Xiao, Z. Z. Yang, L. D. Lu, H. B. Fu, "Synthesis and Characterization of the Layered Zirconium Phosphate and its Intercalation Study", Advanced Materials Research, Vols. 233-235, pp. 1809-1813, 2011
Online since
May 2011
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Hong Yan Xu, Xiao Jun Bao, Ting Hai Wang, Yong Gang Wang
Abstract:The silica-alumina-pillared montmorillonite materials (SiAl-MMT) were developed by a novel method, which combined several techniques such as...
1712
Authors: Xiao Man Du, Qin Fu Liu, Hong Fei Cheng
Abstract:The kaolinite-potassium acetate composite was prepared by the immersion method. The intercalation composites were characterized by means of...
1220
Authors: Bao Zhong Du, Wei Luo, Ru Min Wang
Abstract:Layered double hydroxides (LDHs), consist of cationic brucite-like layers and exchangeable interlayer anions. In this thesis LDHs consist of...
2448
Authors: Jian Qiang Liu, Xing Qi Fu, Jian Ye Song, Yun Xu Fu, Wan Guo Hou
Abstract:In this paper, the intercalation of methyl-orange (MO) into Mg/Al (ratio=2:1) layered double hydroxide (LDH) was carried out using...
753
Authors: Qian Zhu, Dai Mei Chen, Yan Liu, Xu Tao Deng, Hui Li, Zhi Jin Lu
Chapter 2: Materials Science and Engineering
Abstract:Protein-montmorillonite composites were prepared by direct and stepwise intercalation of lysozyme(LYZ) into gallery of montmorillonite(MMT),...
1120