Synthesis of Al-Containing Mesoporous Molecular Sieves and their Catalytic Performance to Isomerization Reaction of Endo-Tetrahydrodicyclo-Pentadiene
| Periodical | Advanced Materials Research (Volumes 233 - 235) |
|---|---|
| Main Theme | Fundamental of Chemical Engineering |
| Edited by | Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He |
| Pages | 234-237 |
| DOI | 10.4028/www.scientific.net/AMR.233-235.234 |
| Citation | Sa Liu et al., 2011, Advanced Materials Research, 233-235, 234 |
| Online since | May, 2011 |
| Authors | Sa Liu, Jian Wei Guo, Chu Fen Yang, Long Huan Li, Yi Hua Cui |
| Keywords | Catalytic Isomerization, Mesoporous Molecular Sieve, Synthesis |
| Price | US$ 28,- |
Al-containing mesoporous molecular sieves(Al-MCM-41) were synthesized at ambient temperature. The structures of samples were characterized by XRD, N2-adsorption/desorption isotherms and FT-IR, etc. The evaluation results showed that Al-MCM-41 had higher catalytic activity for isomerization conversion of endo-tetrahydrodicyclo-pentadiene (endo-TCD) into exo-tetrahydrodicyclo-pentadiene (exo-TCD) and adamantane (AdH). Loading inorganic acid on the surface of Al-MCM-41 led increase of its catalytic activity and the yield of adamantane.