Paper Title:
Effective Aerobic Oxidation of p-Nitrotoluene to p-nitrobenzoic acid Catalyzed by Manganese Dioxide and N-Hydroxyphthalimide
  Abstract

p-Nitrobenzoic acid could be efficiently prepared from aerobic oxidation of p-nitrotoluene using manganese dioxide (MnO2) and N-hydroxyphthalimide (NHPI) as catalysts. The conditions of oxidation were also optimaized: 97 % conversion of p-nitrotoluene and 89 % isolated yield of p-nitrobenzoic acid could be obtained at 110 °C under 0.4 MPa for 4 h in presence of 10 mol% NHPI and 10 mol% MnO2.

  Info
Periodical
Advanced Materials Research (Volumes 233-235)
Edited by
Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He
Pages
317-320
DOI
10.4028/www.scientific.net/AMR.233-235.317
Citation
W. Wang, B. Yan, J. Jiang, G. Y. Yang, "Effective Aerobic Oxidation of p-Nitrotoluene to p-nitrobenzoic acid Catalyzed by Manganese Dioxide and N-Hydroxyphthalimide", Advanced Materials Research, Vols. 233-235, pp. 317-320, 2011
Online since
May 2011
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$32.00
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