Paper Title:
Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols
  Abstract

Disulfides play important roles in biological and chemical processes. Oxidation of thiols is the most exploited method for disulfide synthesis. Trichloromonoxomolybdenum (V) has been found to be a superior oxotransfer reaction catalyst for the conversion of thiols to the corresponding disulfides in excellent yields under mild reaction conditions. A viable kilo-scale synthesis of the symmetrical disulfide was described. Simple workups, economical and practical are the some advantages of this method.

  Info
Periodical
Advanced Materials Research (Volumes 233-235)
Edited by
Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He
Pages
62-65
DOI
10.4028/www.scientific.net/AMR.233-235.62
Citation
W. Li, S. K. Chen, Z. H. Huang, S. X. Fang, C. Li, "Trichloromonoxomolybdenum(V): An Efficient Catalyst for the Preparation of Symmetrical Disulfides from Thiols", Advanced Materials Research, Vols. 233-235, pp. 62-65, 2011
Online since
May 2011
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Price
$32.00
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