Rheological and Flocculated Properties of Silver Nanoparticles Paste

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Silver nanoparticles pastes were formatted by mixing different volumetric silver nanoparticles with the mixture of 12.7wt% bismuth subgallate and 87.3wt% organic vehicle. Rheological and flocculated properties of silver nanoparticles pastes were examined. All pastes demonstrated pseudoplastic flow behaviors and shear thinning characters over the solids-loading and shear-rate range studied. The viscosities of pastes reduce with increasing the shear rate in a logarithmic plot. G' (storage modulus) and G" (loss modulus) increase with increasing silver nanoparticles content and frequency. At high loading, G' and G" begin to level off and exhibit plateau in the low-frequency range. The appearance of the plateau at low frequency is due to the presence of silver nanoparticles in the system and forming the three-dimensional network structure. The shear stress increases with increasing silver nanoparticles content. Apparent yield value estimated by casson equation exhibits a power-law dependence on particle volume fraction.

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Advanced Materials Research (Volumes 236-238)

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2197-2201

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May 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] W. Peng, V. Hurskainen, K. Hashizume, S. Dunford, S. Quander, R. Vatanparast, Elec. Compon. Technol. Conf. (2005), p.77

Google Scholar

[2] H. Dong, Z.g Zhang, C. P. Wong, J. Adhesion Sci. Technol. Vol.19 (2005), p.87

Google Scholar

[2] H.H. Lee, K.S. Chou, K.C. Huang, Nanotechnology Vol.16 (2005), p.2436

Google Scholar

[4] W. W. Kwan, V. Kripesh, M.K. Iyer, M. Gupta, A.A.O. Tay, R. Tummala, Electron. Packag. Technol. Conf.( 2003), p.551

Google Scholar

[5] V. Kardashian, S. Vellanki, IEEE Trans. Compon, Hybrids, Manuf Technol. Vol.2 (1979), p.232

Google Scholar

[6] H. Kanai, R.C. Navarrete, C.W. Macosko, L.E. Scriven, Rheol. Acta. Vol.31 (1992), p.333

Google Scholar

[7] J. F. Feller, S. Bruzaud, Y. Grohens, Mater. Lett. Vol.58 (2004), p.739

Google Scholar

[8] D. J. Shaw, in Introduction to colloid and surface Chemistry, 4th ed. Butterworth-Heinemann, Oxford (1996)

Google Scholar

[9] J. Pugh, O. L. Bergstr: Surface and Colloid Chemistry in Advanced Ceramics processing (Marcel Dekker, Inc., New York, U.S.A., 1994)

Google Scholar

[10] J. T. Wenjea, H. W. Chun, Acta Mater. Vol. 50 (2002), p.3757

Google Scholar

[11] S.Onogi, T. Matsumoto, Polym. Eng. Rev. Vol. 1 (1981), p.45

Google Scholar

[12] N.Casson, Rheology of disperse systems. edtied by C. C. Mill pergamon press, New York (1959)

Google Scholar

[13] Van der Aerschot E, J. Mewis, colloids surf. Vol. 69 (1992), p.15

Google Scholar

[14] Y.G. Yanovsky, Polymer rheology: Theory and practice. Chapman & Hall, London (1993)

Google Scholar