Paper Title:
A New Type of Organic Ferroelectric Material Based on Maleopimaric Acid Anhydride
  Abstract

In this paper, maleopimaric acid anhydride (MPA) has been synthesized by the Diels-Alder addition reaction between abietic acid and maleic anhydride. Single crystal X-ray diffraction analysis reveals that MPA crystallizes in the polar space group P21 and contains one MPA and one DMF (Dimethylformamide) molecule in the asymmetric unit. MPA is firstly found to be a new type of low-molecular-mass organic ferroelectric with the saturation spontaneous polarization (Ps) about 60.0-61.6 μC·cm-2 for single crystal samples, which is close to that of typical inorganic ferroelectric materials. MPA·DMF also shows second-order NLO property, with the second harmonic generation (SHG) responses approximately 0.5 times that of urea.

  Info
Periodical
Advanced Materials Research (Volumes 239-242)
Edited by
Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He
Pages
1180-1183
DOI
10.4028/www.scientific.net/AMR.239-242.1180
Citation
Y. Sui, D. S. Liu, R. H. Hu, "A New Type of Organic Ferroelectric Material Based on Maleopimaric Acid Anhydride", Advanced Materials Research, Vols. 239-242, pp. 1180-1183, 2011
Online since
May 2011
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Price
$32.00
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