Paper Title:
Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity
  Abstract

New 1-D zigzag chain coordination polymer {[HgBr2(pbbm)].DMF}n (1) has been successfully constructed with the aim of exploiting new and potent ion-exchange materials. Remarkably, the coordinated Br- anions in the title polymer can be replaced completely by F-, Cl- and I- anions when the crystals are immersed in the aqueous solutions of the corresponding potassium salts, respectively. This exchange is quantified by FT-IR spectra, the PXRD pattern as well as EDS analyses.

  Info
Periodical
Advanced Materials Research (Volumes 239-242)
Edited by
Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He
Pages
2683-2686
DOI
10.4028/www.scientific.net/AMR.239-242.2683
Citation
B. Xiao, Q. Q. Li, L. J. Yang, S. M. Fang, "Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity", Advanced Materials Research, Vols. 239-242, pp. 2683-2686, 2011
Online since
May 2011
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Price
$32.00
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