Paper Title:
A Dynamically Nanoporous Metal-Organic Framework Functional Properties
  Abstract

3D nanoporous coordination framework [Ni2(nic)4(H2O)]n (nic=Nicotinic acid) was obtained hydrothermally from a mixture of NiCl2.6H2O and 3-cyanopyridine. X-ray single crystal analysis revealed that it consists of “mushroom-shaped” channels along a axis suitable for gas storage. N2-adsorption studies at 77 K revealed a Langmuir surface area of 200 m2/g and a pore volume of 0.12 cm3/g. The compound shows dynamic dehydration and rehydration behaviors with the formation of 0D coordination [Ni(nic)2(H2O)4], accompanied by crystal-to-crystal transformation. The structural transformation significantly changes the character of magnetic exchange interactions and gas storage.

  Info
Periodical
Advanced Materials Research (Volumes 239-242)
Edited by
Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He
Pages
3150-3155
DOI
10.4028/www.scientific.net/AMR.239-242.3150
Citation
X. Huang, L. J. Jiang, M. L. Hu, X. H. Li, "A Dynamically Nanoporous Metal-Organic Framework Functional Properties", Advanced Materials Research, Vols. 239-242, pp. 3150-3155, 2011
Online since
May 2011
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Feng Jie Zhang, Xiao Xia Ou, Chun Qiu Ran, Yun Na Wu
Abstract:Sorption of Pb, Zn, Cu by natural soils was investigated under conditions of variable pH, ionic strength and temperature. The results...
2810
Authors: Li Juan Pang, Yun Gui Chen, Chao Ling Wu, Xue Feng Zhang, Gang Deng
New Energy Materials
Abstract:Mg17Al12and rare earth improved Mg17Al12La0.45 alloys were prepared by resistance...
1351
Authors: Si Yuan Wu, Hong Zheng, Peter G. Weidler, Peng Cai
Chapter 1: Material Science
Abstract:With synthetic wastewater, a comparative study on co-sorption of Zn(II) and As(V) by Fe/Al-PILCs prepared at different calcination...
783
Authors: Xue Feng Liang, Wan Guo Hou, Ying Ming Xu, Lin Wang, Yue Bing Sun
Chapter 1: Environment Materials and Chemical Environment
Abstract:Hydrotalcite-like compounds containing Mg2+, Al3+ and Fe3+ with a constant M2+/M3+ ratio but varying Al3+/Fe3+ ratios have been prepared. The...
86