Paper Title:

Sulfation of Calcined Raw Meal in the Kiln Inlet Housing for the Cement Industry

Periodical Advanced Materials Research (Volume 266)
Main Theme China Postdoctoral Forum on Materials Science and Engineering
Edited by Deliang Chen
Pages 98-101
DOI 10.4028/www.scientific.net/AMR.266.98
Citation Xiao Yan Li et al., 2011, Advanced Materials Research, 266, 98
Online since June, 2011
Authors Xiao Yan Li, Zhi Juan Hu, Xu Chu Ye, Wei Min Yu, Cong Xi Tao
Keywords Cement Industry, Kiln Inlet Housing, Raw Meal, Sulfation
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Abstract

The sulfation behavior of calcined raw meal was investigated in a laboratory fix-bed reactor under conditions typically for SO2 capture in the kiln inlet housing used in cement production. The initial period is characterized with a fast-increasing conversion, while the second period shows a slow-increasing conversion. A desirable temperature exists for sulfation of calcined raw meal. A smaller particle size favors the sulfation reaction. The initial conversion rate is significantly promoted by a higher SO2 concentration. The SEM examinations show that the sulfation process involves nucleation and growth of CaSO4 grains- the sulfation product. Increasing the temperature and extending the time result in fewer but larger CaSO4 grains in the product layer.