Paper Title:
Synthesis and Crystal Structure of [Zn(C14H12N2)(HCO2)2]•2H2O
  Abstract

Reactions of a freshly prepared Zn(OH)2-2x(CO3)x×yH2O precipitate, formic acid with 2,9’-dimethyl-1,10’-phenanthroline in CH3OH/H2O afforded [Zn(C14H12N2)(HCO2)2]·2H2O. The title compound was structurally characterized by X-ray diffraction methods. It consists of complex molecules [Zn(C14H12N2)(HCO2)2] in which Zn atoms are hexa-coordinated by two N atoms of one phenanthroline ligand and four O atoms of two bidentate formate groups. In the crystal, molecules are connected by O–H···O hydrogen bonds forming layers parallel to (010), and the resulting layers are further linked 3D framework along [100] by π-π packing interactions.

  Info
Periodical
Chapter
I. Solid Materials
Edited by
Fei Hu and Beibei Wang
Pages
174-178
DOI
10.4028/www.scientific.net/AMR.279.174
Citation
S. L. Ni, Y. Meng, P. S. Tang, "Synthesis and Crystal Structure of [Zn(C14H12N2)(HCO2)2]•2H2O", Advanced Materials Research, Vol. 279, pp. 174-178, 2011
Online since
July 2011
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$32.00
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