Paper Title:
Preparation and X-Ray Crystal Structure of Layered Ca(II) Complex Material
  Abstract

A novel Ca(II) complex material was prepared by reaction of O-nitrobenzaldehyde- 3-amino-benzenesulfonic acid with Ca(ClO4)2, and characterized by X-ray single crystal diffraction method. The analytical results shows that the Ca(II) complex was crystallized in the monoclinic system, space group P2(1)/c, with a = 17.515(10) Å, b = 7.019(4) Å, c = 13.853(8) Å, β = 104.855(10) º, V = 1646.3(17) Å3, Z = 2. The geometry of Ca(II) is a slightly distorted dodecahedrall geometry. In the crystal packing, the complex molecules form layered structure by the π-π packing interaction, and the molecules form a one-dimensional chain structure by hydrogen bonds.

  Info
Periodical
Advanced Materials Research (Volumes 282-283)
Chapter
Chapter 1: Material Engineering, Chemistry, Bioinformatics
Edited by
Helen Zhang and David Jin
Pages
108-111
DOI
10.4028/www.scientific.net/AMR.282-283.108
Citation
X. S. Tai, "Preparation and X-Ray Crystal Structure of Layered Ca(II) Complex Material", Advanced Materials Research, Vols. 282-283, pp. 108-111, 2011
Online since
July 2011
Authors
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Xia Wang, Ming Qing Xing
Chapter 12: Materials and its Applications
Abstract:Large single crystal of Na2Ni (SO4)2.4H2O (NNSH) was grown for the first time using method of isothermal decrease of supersaturation. The...
1735
Authors: Yan Na Li, Shu Kun Lin
Chapter 11: Analytical Chemistry and Environmental Chemistry
Abstract:Single crystal of 5-sulfosalicylato potassium was grown by the method of slow cooling in solution. The crystal shows a good cleavability...
1929
Authors: Feng Miao, Ying Huang
Chapter 09: Materials Science
Abstract:Considering the crystal field parameter B, C and average covalent factor N, the energy levels of Li2GeO3: Cr3+ crystal are calculated by...
906