Paper Title:
Synthesis of Carbazoled Poly(Arylene Imino)
  Abstract

The carbazoled poly(arylene imino)s (c-PAI) have been synthesized via palladium-catalyzed polycondensation of 3,6-diamino-N-(2-ethylhexyl)carbazole with different aromatic dibromides. The structure of c-PAI were characterized by means of FT-IR, 1H NMR spectroscopy and elemental analysis, the results show an agreement with the proposed structure. The thermal properties of c-PAI were detected by DSC and TG. The result show that the polymers possess high glass transition temperature (Tg>250°C ), good thermal stability with high decomposition temperatures (TD>410°C), In addition to the thermal properties, the optical properties were studied, including Uv-vis absorption, photoluminescence and time of flight (TOF).

  Info
Periodical
Advanced Materials Research (Volumes 284-286)
Chapter
High Performance Elastomers & Polymers
Edited by
Xiaoming Sang, Pengcheng Wang, Liqun Ai, Yungang Li and Jinglong Bu
Pages
1863-1866
DOI
10.4028/www.scientific.net/AMR.284-286.1863
Citation
W. W. Shan, G. J. Chang, F. H. Zhu, L. Zhang, "Synthesis of Carbazoled Poly(Arylene Imino)", Advanced Materials Research, Vols. 284-286, pp. 1863-1866, 2011
Online since
July 2011
Export
Price
$32.00
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