Paper Title:
Novel Terbium-Cerium Coordination Polymer: Synthesis, Characterization and Fluorescence Properties
  Abstract

Using a polyaryletherketone bearing carboxyl groups (PEK) as macromolecular ligand, Tb3+ and Ce3+ as central coordination ions, 1,10-phenanthroline (Phen) as the second ligand, a kind of novel terbium-cerium coordination polymer (PEK-Tb3+0.5Ce3+0.5-Phen) was prepared. The structure of PEK-Tb3+0.5Ce3+0.5-Phen was investigated by ICP, FTIR and XRD. The results showed that Tb3+ and Ce3+ ions coordinated to both the polymer ligand PEK and the second ligand Phen, and rare earth ions homogeneously distributed in the polymer matrix. The fluorescence measurement indicated that PEK-Tb3+0.5Ce3+0.5-Phen can exhibit the characteristic emission of Tb3+. Furthermore, the emission intensity of PEK-Tb3+0.5Ce3+0.5-Phen at 546 nm, corresponding to the green color, was higher than that of PEK-Tb3+-Phen.

  Info
Periodical
Advanced Materials Research (Volumes 284-286)
Chapter
Optical/Electronic/Magnetic Materials
Edited by
Xiaoming Sang, Pengcheng Wang, Liqun Ai, Yungang Li and Jinglong Bu
Pages
2198-2201
DOI
10.4028/www.scientific.net/AMR.284-286.2198
Citation
D. Liu, Z. G. Wang, D. P. Zhou, D. W. Huang, H. M. Wang, Y. Lian, "Novel Terbium-Cerium Coordination Polymer: Synthesis, Characterization and Fluorescence Properties", Advanced Materials Research, Vols. 284-286, pp. 2198-2201, 2011
Online since
July 2011
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$32.00
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