Paper Title:
Oxidative Dehydrogenation of Cyclohexane over Mg-V-O Catalysts Prepared via Citriate Complexation
  Abstract

Oxidative dehydrogenation of cyclohexane was studied over three pure Mg-V-O catalysts, which are Mg3(VO4)2, Mg2V2O7 and MgV2O6, respectively. Catalysts were prepared via citric acid complexation and characterized by N2-adsorption, XRD, FT-IR, NH3-TPD and H2-TPR techniques. Among the pure magnesium vanadates, Mg3(VO4)2 has the isolated active sites, weakly basic surface and lower reducibility of the metal cations, and could be recognized as the catalytic active phase. Mg3(VO4)2 catalyst exhibited a better catalytic performance, on which a cyclohexene selectivity of 41.5% at cyclohexane conversion of 15.5% was obtained.

  Info
Periodical
Advanced Materials Research (Volumes 284-286)
Chapter
Micro/Nano Materials
Edited by
Xiaoming Sang, Pengcheng Wang, Liqun Ai, Yungang Li and Jinglong Bu
Pages
692-696
DOI
10.4028/www.scientific.net/AMR.284-286.692
Citation
M. Jin, P. Lu, G. X. Yu, "Oxidative Dehydrogenation of Cyclohexane over Mg-V-O Catalysts Prepared via Citriate Complexation", Advanced Materials Research, Vols. 284-286, pp. 692-696, 2011
Online since
July 2011
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Price
$32.00
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