Paper Title:
A Novel Catalyst for the Preparation of Biodegradable Polycarbonate from Carbon Dioxide
  Abstract

A catalyst of BTPD-Zn (BTPD= N,N’-Bis(2-thiophenecarboxaldehy) o-phenylenediamine) has been found to be active toward the copolymerization of cyclohexene oxide and carbon dioxide, and a kind of good biodegradable material named poly(cyclohexene carbonate) is prepared with turnover number of 105.8 in 100°C. The molar fraction (fc) of polycarbonate in copolymer is 96%. The obtained copolymers were characterized by IR and NMR.

  Info
Periodical
Advanced Materials Research (Volumes 287-290)
Chapter
Environmental Catalysis and Environmental Friendly Materials
Edited by
Jinglong Bu, Pengcheng Wang, Liqun Ai, Xiaoming Sang, Yungang Li
Pages
1761-1764
DOI
10.4028/www.scientific.net/AMR.287-290.1761
Citation
G. Qin, L. D. Fan, R. Zhang, S. K. Cao, "A Novel Catalyst for the Preparation of Biodegradable Polycarbonate from Carbon Dioxide", Advanced Materials Research, Vols. 287-290, pp. 1761-1764, 2011
Online since
July 2011
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Price
$32.00
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