Paper Title:
Electro-Generation of 2, 3, 5, 6-TCP in Zn, Ni,P-mSA/mCS Bipolar Membrane Equipped Electrolysis Cell
  Abstract

P-ferrocene-SA/acetylferrocene-CS Bipolar Membrane (BPM) was prepared with phosphorylated agent as the cation exchange layer, and chitosan (CS) modified with acetylferrocene as the anion exchange layer. Zinc/Nickel alloy layer was placed on the surface of cation exchange layer to realize zero polar distance in the cathode chamber. The 2, 3, 5, 6-tetrachlopyridine (2,3,5,6-TCP) was electro-synthesized by reducing of pentachloropyridine(PCP). At the current density of 30mA·cm-2, the current efficiency was 70.1% and the yield of 2, 3, 5, 6-TCP was up to 96%. Compared with the traditional method, the electro-generation technology greatly eliminated the environmental pollution.

  Info
Periodical
Advanced Materials Research (Volumes 295-297)
Chapter
Chapter 1: Materials Properties
Edited by
Pengcheng Wang, Liqun Ai, Yungang Li, Xiaoming Sang and Jinglong Bu
Pages
1074-1078
DOI
10.4028/www.scientific.net/AMR.295-297.1074
Citation
H. F. Xie, Y. C. Xiao, S. B. Li, C. Zhen, "Electro-Generation of 2, 3, 5, 6-TCP in Zn, Ni,P-mSA/mCS Bipolar Membrane Equipped Electrolysis Cell", Advanced Materials Research, Vols. 295-297, pp. 1074-1078, 2011
Online since
July 2011
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Price
$32.00
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