Paper Title:
Catalytic Synthesis of Dioctyl Phthalate over Al-MCM-41 Molecular Sieves
  Abstract

In this paper, mesoporous MCM-41 and Al-MCM-41(Si/Al =100, 70, 40, 10, 5) molecular sieves were synthesized by direct hydrothermal process and characterized by various analytical techniques. Their catalytic performance in the synthesis of dioctyl phthalate (DOP) was also studied. The results show that while keeping the mesostructure of Al-MCM-41(Si/Al=100, 70, 40), increasing Al content can increase the acidity and so forth effectively improve the catalytic activity. But too much aluminum incorporation can destroy the structure of Al-MCM-41(Si/Al=10). The Al-MCM-41 molecular sieves with proper Si/Al ratios have good catalytic activity and stability in DOP synthesis. When Al-MCM-41(40) was used as the catalyst, A high PA conversion of 98.45% can be reached in 4 h. After being reused for five times, Al-MCM-41(40) still remains good catalytic activity.

  Info
Periodical
Advanced Materials Research (Volumes 306-307)
Edited by
Shiquan Liu and Min Zuo
Pages
1741-1746
DOI
10.4028/www.scientific.net/AMR.306-307.1741
Citation
H. F. Zhou, Y. J. Yang, J. S. Zhang, "Catalytic Synthesis of Dioctyl Phthalate over Al-MCM-41 Molecular Sieves", Advanced Materials Research, Vols. 306-307, pp. 1741-1746, 2011
Online since
August 2011
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Price
$32.00
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