In order to reduce friction coefficient of the Ni-base alloy coating and further improve its wear resistance, the graphite/TiC/Ni-base alloy composite coating was prepared on the surface of 45 carbon steel by plasma spray. Effects of loads, friction counterparts and lubricants on tribological properties of the coating were investigated. The results show that friction coefficient of the composite coating is reduced by 33% than that of the Ni-base alloy coating when worn against GCr15. Wear losses of the composite coating are less than those of the Ni-base alloy coating at all loads of 6N, 8N, 10N and 12N. Worn against Si3N4, friction coefficient of the composite coating is 13% less than that worn against GCr15, but its wear loss is 2.9 times of that worn against GCr15. Wear mechanism of the composite coating is micro cutting and brittle fraction when worn against Si3N4. Under lubrication of NaCl solution, friction coefficient of the composite coating is almost the same as that under dry sliding, wear loss is increased by 1.6 times. Stress corrosion and wedging effects of the NaCl solution are main wear mechanisms of the composite coating.