The waste of office is a major source of municipal solid waste. Taking the imperfect and poor-running recycling system into account, we may start with establishing a pilot recycling system in China’s urban areas, in the hope of exploring its organizational and operational mechanisms. A questionnaire-based survey among the office staff is implemented. According to the results, this paper preliminarily proves the feasibility of setting up an efficiency-led office waste recycling system. What’s more, the framework and operational mechanism of a new pilot recycling system is designed.