Paper Title:
Preparation of Recyclable Pd(II) Organometal Catalyst with Bicontinuous Cubic Ia3d Mesostructure for Water-Medium Organic Reaction
  Abstract

A heterogenous Pd(II) organometal catalyst with bicontinuous cubic Ia3d mesostructure was synthesized by surfactant-directed co-condensation of Pd[PPh2(CH2)2Si(OCH2CH3)3]2Cl2 and (CH3CH2O)3SiPhSi(OCH2CH3)3. In water medium Sonogashira reaction, the as-prepared Pd(II)-PMO-KIT-6 exhibited higher catalytic activity than the corresponding Pd(II)-KIT-6 catalyst and could be used repetitively for more than 4 times, which could reduce the cost and even diminish the environmental pollution from heavy metallic ions, showing a good potential in industrial applications.

  Info
Periodical
Advanced Materials Research (Volumes 356-360)
Chapter
Chapter 2: Environmental Materials
Edited by
Hexing Li, Qunjie Xu and Daquan Zhang
Pages
407-410
DOI
10.4028/www.scientific.net/AMR.356-360.407
Citation
D. D. Yang, F. X. Zhu, H. X. Li, "Preparation of Recyclable Pd(II) Organometal Catalyst with Bicontinuous Cubic Ia3d Mesostructure for Water-Medium Organic Reaction", Advanced Materials Research, Vols. 356-360, pp. 407-410, 2012
Online since
October 2011
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Price
$32.00
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